Distribution of Forms of Zinc and Their Association with Soil Properties and Uptake in Different Soil Orders in Semi‐arid Soils of Punjab, India

Abstract

Abstract Profiles of semi‐arid–zone soils in Punjab, northwest India, were investigated for different forms of zinc (Zn), including total, diethylenetriamine penta‐acetic acid (DTPA)-extractable, soil solution plus exchangeable (Zn), Zn adsorbed onto inorganic sites, Zn bound by organic sites, and Zn adsorbed onto oxide surfaces. Irrespective of the different fractions of Zn present, its content was higher in fine‐textured Alfisols and Inceptisols than in coarse‐textured Entisols. In general, the higher content of Zn was observed in the surface horizon and then decreased in the subsurface horizons. However, none of the forms of Zn exhibited any consistent pattern of distribution. Organic matter and size fractions (clay and silt) had a strong influence on the distribution of different forms of Zn. Based upon the linear coefficient of correlation, the soil solution plus exchangeable Zn, adsorbed onto inorganic sites, and DTPA‐Zn increased with increase in organic carbon but decreased with increase in pH and calcium carbonate content. Total Zn increased with increase in clay and silt content. Among the different forms, Zn bound by organic sites, water soluble plus exchangeable Zn and Zn adsorb onto oxide (amorphous surfaces) were all correlated with DTPA extractable Zn. The uptake of Zn was more in recent floodplain Entisols than very fine textured Alfisols and Inceptisols. Among the different forms soil solution +exchangeable and DTPA‐extractable Zn was positively correlated with total uptake of Zn.