Chiral‐at‐Metal Octahedral Iridium Catalyst for the Asymmetric Construction of an All‐Carbon Quaternary Stereocenter

Abstract

Metall-vermittelte Organokatalyse: Der enantioselektive Aufbau quartärer Stereozentren wird durch die Ligandensphäre eines inerten bis-cyclometallierten Iridiumkomplexes (siehe Bild) katalysiert. In diesem Komplex dient allein die metallzentrierte Chiralität als Quelle für die effektive asymmetrische Induktion. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.