Zeitschrift für anorganische und allgemeine Chemie · 1972 · 10 citations · 5 references
Natural SciencesChemistryCrystal StructureInorganic ChemistrySpectroscopyCoordination ChemistryCrystal ChemistryCrystal Field TheoryMagnetism Of Inorganic CompoundsMetal-ligand BondingTransition Metal ComplexesCrystal Field ParametersCrystal-field EffectsElectronic Spectra Of Transition Metal ComplexesLigand Field EffectsMagnetic Properties Of Coordination ComplexesMagnetic Properties Of Transition Metal ComplexesMagnetism Of Transition Metal ComplexesNuclear Magnetic Resonance Studies
Abstract A series of carbonato‐ammine cobalt(III) Complexes were prepared. The chemical shifts observed in 59 Co n. m.r. in these complexes have been explained on the basis of the theory of G RIFFITH and O RGEL . The relative order of ligand field strength obtained from n. m.r. data is in good agreement with the optical data. The splittings of the bands the visible and near u.v. region were examined, and the various crystal field parameters (Dq′ B, Dt′) are discussed.
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