Gold‐Catalyzed Tandem Cyclization of Dienol Silyl Ethers for the Preparation of Bicyclo[4.3.0]nonane Derivatives

Abstract

Über den Fünfring zum Sechsring: Eine goldkatalysierte geminale Carbofunktionalisierung von 3-Siloxy-1,3-dien-8-inen führte über die Ringerweiterung eines bicyclischen Carbenkomplexes glatt und stereoselektiv zu Bicyclo[4.3.0]nonanen. Das Produkt unterschied sich in seiner Konfiguration von dem Produkt einer thermischen Diels-Alder-Addition. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.