Synthesis of the A ring segment of gambieric acid

Asymmetric alkylation reactions of chiral imide enolates. A practical approach to the enantioselective synthesis of .alpha.-substituted carboxylic acid derivatives

David A. Evans, Michael D. Ennis, David J. Mathre · Journal of the American Chemical Society · 1982 · 1K citations

Natural Sciences, Chemistry, Catalysis +11

Chiral synthesis via organoboranes. 7. Diastereoselective and enantioselective synthesis of erythro- and threo-.beta.-methylhomoallyl alcohols via enantiomeric (Z)- and (E)-crotylboranes

Herbert C. Brown, K. S. BHAT · Journal of the American Chemical Society · 1986 · 380 citations

Natural Sciences, Chemistry, Natural Product Biosynthesis +5

Chiral synthesis via organoboranes. 27. Remarkably rapid and exceptionally enantioselective (approaching 100% ee) allylboration of representative aldehydes at -100.degree. under new, salt-free conditions

Uday S. Racherla, Herbert C. Brown · The Journal of Organic Chemistry · 1991 · 357 citations

Natural Sciences, Chemistry, Catalysis +6

Enantiomeric Z- and E-crotyldiisopinocampheylboranes. Synthesis in high optical purity of all four possible stereoisomers of .beta.-methylhomoallyl alcohols

Herbert C. Brown, K. S. BHAT · Journal of the American Chemical Society · 1986 · 324 citations

Natural Sciences, Chemistry, Carbohydrate Chemistry +5

Gambieric acids, new potent antifungal substances with unprecedented polyether structures from a marine dinoflagellate Gambierdiscus toxicus

Hiroshi Nagai, Michio Murata, Koichiro Torigoe et al. · The Journal of Organic Chemistry · 1992 · 187 citations

Natural Sciences, Marine Biology, Marine Sciences +14