Selective Intermolecular Amination of CH Bonds at Tertiary Carbon Centers

Abstract

C-H-Insertion: Eine Methode für die intermolekulare Aminierung von C-H-Bindungen wird beschrieben, die limitierende Substratmengen und eine bequeme, Phenol-abgeleitete Stickstoffquelle einsetzt. Selektivitäts- und mechanistische Studien ergeben, dass die sterische Wechselwirkung zwischen dem Substrat und dem aktiven Oxidans entscheidend für die Produktselektivität ist. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.