Concepedia

Synthesis and Properties of Conducting Bridged Macrocyclic Metal Complexes

Michael Hanack, Wolfram Kobel, J. Koch, Josef Metz, O. Schneider, Hans‐Joachim Schulze

Molecular crystals and liquid crystals · 1983 · 11 citations · 3 references

DOI

Concepts

Abstract

Abstract The synthesis and the properties of polymeric phthalocyaninatometal complexes of the type shown in figure 1 are described. In addition to pyrazine (pyz) and 1, 4-diisocyanobenzene (dib) the cyano-group is used as a bridging ligand for the first time such leading to μ-cyanophthalocyaninatocobalt(III) (10). 10 shows a conductivity of 10−2 S · cm−1 (powder, compressed pellets) at room temperature without iodine-doping.

References

3

Polymere Dimethyl-und Diphenylglyoximatokomplexe des Cobalts und Eisens mit Pyrazin als Brückenligand. Die Kristallstruktur des Bis(dimethylglyoximato)pyrazin-cobalt(II) <sup>+</sup> / Polymeric Dimethyl-and Diphenylglyoximato Complexes of Cobalt and Iron with Pyrazine as a Bridging Ligand. The Crystal Structure of Bis(dimethylglyoximato)pyrazine Cobalt(II)<sup>+</sup>

F. Kubel, Joachim Strähle · Zeitschrift für Naturforschung B · 1981 · 50 citations · Full text

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Strategies for Control of Lattice Architecture in Low-Dimensional Molecular Metals: Assembly of Partially Oxidized Face-to-Face Linked Arrays of Metallomacrocycles

Carl W. Dirk, Eric A. Mintz, K.F. Schoch et al. · Journal of Macromolecular Science Part A - Chemistry · 1981 · 49 citations

, , +17

Synthesis and Properties of a New Kind of One-Dimensional Conductors 17. Studies on monomeric and polymeric phthalocyaninato-iron(II) and -cobalt(II) complexes

O. Schneider, Josef Metz, M. Hanack · Molecular crystals and liquid crystals · 1982 · 39 citations

, , +14