CH Functionalization Logic Enables Synthesis of (+)‐Hongoquercin A and Related Compounds

Brandon R. Rosen, Leah R. Simke, Peter Thuy-Boun, Darryl D. Dixon, Jin‐Quan Yu, Phil S. Baran

Angewandte Chemie · 2013 · 56 citations · 49 references

Concepts

Abstract

Ganz spezifisch: Eine Synthese des antibiotischen Sesquiterpenoids (+)-Hongoquercin A über sequenzielle regiospezifische C-H-Methylierung und C-H-Oxidation wird beschrieben. Die Synthese beruht entscheidend auf der Entwicklung einer ligandbeschleunigten C-H-Methylierung. Acht strukturell diverse Analoga wurden synthetisiert. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

References

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