Concepedia

Chemical Effects on Linewidths Observed in Photoelectron Spectroscopy

Richard M. Friedman, J. Hudis, M. L. Perlman

Physical Review Letters · 1972 · 61 citations · 3 references

DOI

Concepts

Abstract

Widths of photoelectron lines associated with vacancies in core levels immediately below the valence shell are shown to depend on the chemical environment. The width variation is ascribed to change in vacancy lifetime. Valence electron density influences these lifetimes through its effect on Auger transition rates. Correlation of linewidth and chemical shift in electron binding energy is discussed.

References

3

Atomic L-Shell Coster-Kronig, Auger, and Radiative Rates and Flourescence Yields for Na-Th

E. J. McGuire · Physical review. A, General physics · 1971 · 453 citations

, , +8

<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mi>K</mml:mi></mml:math>-Shell Auger Transition Rates and Fluorescence Yields for Elements Be-Ar

E. J. McGuire · Physical Review · 1969 · 346 citations

, , +10

The electronic structure of carbon suboxide from ESCA and AB initio calculations

U. Gelius, C.J. Allan, David A. Allison et al. · Chemical Physics Letters · 1971 · 84 citations

, , +14