Angewandte Chemie International Edition · 2006 · 128 citations · 27 references
Natural SciencesChemistryMaterials ScienceCrystal StructureInorganic ChemistryOptical MaterialsCrystal ChemistryFluorescence SpectroscopyLuminescent MaterialsPhotochemistryRare-earth-doped MaterialsEmission Spectra AnalysisFramework SubstitutionRare-earth-doped CrystalsRare-earth-doped Luminescent MaterialsZeolites
All the colors of the rainbow can be observed upon excitation of a zeolite crystal incorporated with varying quantities of Eu3+ and Tb3+ ions as well as a sensitizer molecule (benzophenone or 4-acetylbiphenyl) in its framework structure (see picture). The colors can be fine-tuned by varying the amounts of the three components as well as the excitation wavelength and temperature.
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