Concepedia

Practical Imidazole‐Based Phosphine Ligands for Selective Palladium‐Catalyzed Hydroxylation of Aryl Halides

Thomas Schulz, C. Torborg, Benjamín Schäffner, Jun Huang, Alexander Zapf, Renat Kadyrov, Armin Börner, Matthias Beller

Angewandte Chemie · 2008 · 211 citations · 52 references

DOI

Concepts

Abstract

Phenol-menal: Bis zu 100 g von neuartigen Imidazol-Phosphan-Liganden wurden nach einem bequemen Lithiierungs-Phosphorylierungs-Protokoll synthetisiert. Die luft- und feuchtigkeitsbeständigen Phosphane erwiesen sich in der palladiumkatalysierten selektiven Hydroxylierung von Arylhalogeniden als erfolgreich (siehe Schema, dba = Dibenzylidenaceton).

References

52

Expanding Pd-Catalyzed C−N Bond-Forming Processes:  The First Amidation of Aryl Sulfonates, Aqueous Amination, and Complementarity with Cu-Catalyzed Reactions

Xiaohua Huang, Kevin W. Anderson, Danilo Zim et al. · Journal of the American Chemical Society · 2003 · 767 citations

, , +16

Room-Temperature Palladium-Catalyzed Amination of Aryl Bromides and Chlorides and Extended Scope of Aromatic C−N Bond Formation with a Commercial Ligand

John F. Hartwig, Motoi Kawatsura, Sheila I. Hauck et al. · The Journal of Organic Chemistry · 1999 · 764 citations

, , +9

Air Stable, Sterically Hindered Ferrocenyl Dialkylphosphines for Palladium-Catalyzed C−C, C−N, and C−O Bond-Forming Cross-Couplings

Noriyasu Kataoka, Quinetta D. Shelby, James P. Stambuli et al. · The Journal of Organic Chemistry · 2002 · 729 citations

, , +16

A Convenient and General Method for Pd-Catalyzed Suzuki Cross-Couplings of Aryl Chlorides and Arylboronic Acids

Adam F. Littke, Gregory C. Fu · Angewandte Chemie International Edition · 1998 · 702 citations

, , +10

Simple, Efficient Catalyst System for the Palladium-Catalyzed Amination of Aryl Chlorides, Bromides, and Triflates

John P. Wolfe, Hiroshi Tomori, Joseph P. Sadighi et al. · The Journal of Organic Chemistry · 2000 · 683 citations

, , +16