IEEE Transactions on Components Hybrids and Manufacturing Technology · 1992 · 23 citations · 2 references
Natural SciencesElectrical EngineeringMaterials ScienceCorrosion ScienceHeat TransferMetallic MaterialsElectrical ConductivityFire-resistant MaterialsHigh-temperature CorrosionHigh-temperature OxidationMetallic BondingMetalsCopper CorrosionCorrosion Of Copper AlloysMetal-metal ContactsNegative Temperature CoefficientOxidationRapid Thermal OxidationTemperature Effects On CorrosionThermal Effects In Conductors
Laboratory experiments are reported that show that when a current-carrying loose copper wire connection is exposed to mechanical vibrations, a layer of Cu/sub 2/O grows to form a bridge between the contact members, bonding them to one another. Due to the strongly negative temperature coefficient of Cu/sub 2/O at high temperatures, the current is concentrated in a thin, glowing filament at or near the surface of the oxide bridge. The maximum temperature of this filament was found to be 1200-1300 degrees C. Under the action of this hot filament, a rapid oxidation of the copper continues until most of the circumference of the copper wires is converted to Cu/sub 2/O to a depth of a few tenths of a millimeter. As the corrosion proceeds, the power dissipation increases to values that can cause fire hazards. The phenomenon described explains how a temperature high enough to initiate a fire can arise, even when the current through the connection is limited by the load impedance to values less than 1 A.< <ETX xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">></ETX>
2
Electronic Processes in Ionic Crystals
H. Fröhlich · Nature · 1949 · 1.3K citations · Full text
Natural Sciences, Chemistry, Physics +14