Concepedia

Direct Substitution of the Hydroxy Group in Alcohols with Silyl Nucleophiles Catalyzed by Indium Trichloride

Makoto Yasuda, Takahiro Saito, Masako Ueba, Akio Baba

Angewandte Chemie · 2004 · 49 citations · 11 references

DOI

Concepts

Abstract

Sei nicht sauer! Ein Silylnucleophil kombiniert mit einem Indiumkatalysator wurde zur Dehydroxylierung/Alkylierung von Alkoholen unter fast neutralen Bedingungen eingesetzt (siehe Schema). Üblicherweise erfordert dieser Reaktionstyp äquimolare Mengen an Säure.

References

11

(π-Allyl)palladium Complexes Bearing Diphosphinidenecyclobutene Ligands (DPCB):  Highly Active Catalysts for Direct Conversion of Allylic Alcohols

Fumiyuki Ozawa, Hideyuki Okamoto, Seiji Kawagishi et al. · Journal of the American Chemical Society · 2002 · 376 citations

, , +16

Direct Reduction of Alcohols:  Highly Chemoselective Reducing System for Secondary or Tertiary Alcohols Using Chlorodiphenylsilane with a Catalytic Amount of Indium Trichloride

Makoto Yasuda, Yoshiyuki Onishi, Masako Ueba et al. · The Journal of Organic Chemistry · 2001 · 197 citations

, , +13

Ruthenium-Catalyzed Propargylation of Aromatic Compounds with Propargylic Alcohols

Yoshiaki Nishibayashi, Masato Yoshikawa, Youichi Inada et al. · Journal of the American Chemical Society · 2002 · 166 citations

, , +10

B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>-Catalyzed Allylation of Secondary Benzyl Acetates with Allylsilanes

Michael Rubin, Vladimir Gevorgyan · Organic Letters · 2001 · 119 citations

, , +7

Novel Synthetic Usage of Indium Compounds as Catalyst: Reductive Deoxygenation of Aryl Ketones and <i>sec</i>-Benzylic Alcohols

Takashi Miyai, Masako Ueba, Akio Baba · Synlett · 1999 · 72 citations

, , +11