Stability Constants of Scandium Complexes. I. Monocarboxylate Complexes Species

Abstract

Abstract The stability constants of scandium complexes with some carboxylate ligands were determined potentiometrically at 25.0 and 40.0 °C and at an ionic strength of 0.10 with potassium nitrate as supporting electrolyte. The constants of the scandium complexes were appreciably greater than those of the corresponding lanthanoid complexes, as expected. The changes in free energy, enthalpy, and entropy for the formation of the scandium complexes were calculated from the stability constants at two temperatures.