Photoswitching of the Dielectric Constant of the Spin‐Crossover Complex [Fe(L)(CN)₂]⋅H₂O

Abstract

Photochemisches Schalten der Dielektrizitätskonstante trifft man erstmalig in dem Spin-Crossover-Komplex [Fe(L)(CN)2]⋅H2O an (siehe Bild; L=2,13-Dimethyl-6,9-dioxa-3,12,18-triazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaen). Die elektrische Detektion des photoinduzierten Wechsels des Spinzustands lässt derartige Komplexe für optische Informationsspeicher interessant erscheinen. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2006/z503252_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.