Stereoselective Coordination of <i>C</i>₅‐Symmetric Corannulene Derivatives with an Enantiomerically Pure [Rh^I(nbd*)] Metal Complex

Abstract

Selektiv eingepasst: Enantiomerenreine RhI-Dimethylnorbornadien-Fragmente fangen äquilibrierende Enantiomere C5-symmetrischer pentasubstituierter Corannulenderivate in einer spezifischen Schalenform ab und ermöglichen so die Isolierung eines enantiomerenreinen Metall-Buckybowl-Komplexes. Ein quantenmechanisches Modell (siehe Bild) beschreibt den Mechanismus der molekularen Dynamik und den Grad der stereoselektiven Erkennung. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.