Steric and Electronic Properties of N-Heterocyclic Carbenes (NHC):  A Detailed Study on Their Interaction with Ni(CO)₄

Reto Dorta, Edwin D. Stevens, Natalie Scott, +4

Journal of the American Chemical Society

Inorganic CompoundInorganic ChemistryChemical EngineeringEngineeringHeterocyclic +10

Interaction of a Bulky <i>N</i>-Heterocyclic Carbene Ligand with Rh(I) and Ir(I). Double C−H Activation and Isolation of Bare 14-Electron Rh(III) and Ir(III) Complexes

Natalie Scott, Reto Dorta, Edwin D. Stevens, +3

Journal of the American Chemical Society

Inorganic CompoundInorganic ChemistryChemical EngineeringUnusual RhodiumEngineering +10

Thermodynamics of N-Heterocyclic Carbene Dimerization: The Balance of Sterics and Electronics

Albert Poater, Francesco Ragone, S. Giudice, +4

Organometallics

EngineeringNew NhcsOrganic ChemistryMonomeric NhcsChemistry +16

Comparing the Enantioselective Power of Steric and Electrostatic Effects in Transition‐Metal‐Catalyzed Asymmetric Synthesis

Albert Poater, Francesco Ragone, Ronaldo Mariz, +2

Chemistry - A European Journal

Stable, Three-Coordinate Ni(CO)₂(NHC) (NHC = <i>N</i>-Heterocyclic Carbene) Complexes Enabling the Determination of Ni−NHC Bond Energies

Reto Dorta, Edwin D. Stevens, Carl D. Hoff, +1

Journal of the American Chemical Society

Inorganic ChemistryChemical EngineeringFour-coordinate NiEquilibrium ConditionsEngineering +10

A Chiral Bis-Sulfoxide Ligand in Late-Transition Metal Catalysis; Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to Electron-Deficient Olefins

Ronaldo Mariz, Xinjun Luan, Michele Gatti, +2

Journal of the American Chemical Society

Synthesis of 3‐Fluoro‐3‐aryl Oxindoles: Direct Enantioselective α Arylation of Amides

Linglin Wu, Laura Falivene, E. Drinkel, +4

Angewandte Chemie International Edition

Double C−H Activation in a Rh−NHC Complex Leading to the Isolation of a 14-Electron Rh(III) Complex

Reto Dorta, Edwin D. Stevens, Steven P. Nolan

Journal of the American Chemical Society

Inorganic ChemistrySolvent-dependent InteractionEngineering14-Electron RhNatural Sciences +11

Matching the Chirality of Monodentate N-Heterocyclic Carbene Ligands: A Case Study on Well-Defined Palladium Complexes for the Asymmetric α-Arylation of Amides

Xinjun Luan, Ronaldo Mariz, Carine Robert, +4

Organic Letters

Inorganic ChemistryMonodentate N-heterocyclic CarbeneCross-coupling ReactionEngineeringN-heterocyclic Carbene Ligands +11

Identification and Characterization of a New Family of Catalytically Highly Active Imidazolin-2-ylidenes

Xinjun Luan, Ronaldo Mariz, Michele Gatti, +5

Journal of the American Chemical Society

Inorganic CompoundInorganic ChemistryNew FamilyNhc StructuresEngineering +13