Concepedia

Cuprophilicity: Spectroscopic and Structural Evidence for Cu−Cu Bonding Interactions in Luminescent Dinuclear Copper(I) Complexes with Bridging Diphosphane Ligands

Chi‐Ming Che, Zhong Mao, Vincent M. Miskowski, Man-Chung Tse, Chi-Keung Chan, Kung‐Kai Cheung, David Lee Phillips, King-Hung Leung

Angewandte Chemie · 2000 · 56 citations · 31 references

DOI

Concepts

Abstract

Die eindeutige Zuordnung der 3 dσ*→4 pσ-Metall-Metall-Übergänge anhand spektroskopischer und struktureller Untersuchungen belegt die Existenz cuprophiler CuI⋅⋅⋅CuI-Wechselwirkungen in diskreten zweikernigen, Diphosphan-verbrückten CuI-Komplexen (siehe Bild). Die an den CuI-Zentren beobachtete Lumineszenz hängt in erster Linie von den Metall-Ligand-Bindungen ab.

References

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