Strong, Healable, Stimulus‐Responsive Fluorescent Elastomers Based on Assembled Borate Dynamic Nanostructures

Abstract

Self-healing materials integrated with robust mechanical property and fascinating functions synchronously hold great prospects in many applications, but it still remains a grand challenge. Here, a bottom-up assembly method of preparing borate dynamic nanostructures (BDN) with controllable morphologies and interfacial crosslinks is proposed, from which a robust self-healing elastomer is fabricated. The BDN is optimized to construct dense and strong interfacial boronic easter crosslinks, endowing the elastomer with outstanding stretchability (2050%), high strength (17.9 MPa) as well as healing efficiency (77.1%). Moreover, the elastomer also exhibits pH stimulus-responsive fluorescence property and excellent functional repairability, enabling its potential application in intelligent material fields such as information encoding and encryption. This study demonstrates a general approach to produce self-healable functional materials with robust mechanical properties, and defines a rich platform for exploring various functional nanostructured materials.