Optically Pumped Terahertz Molecular Laser: Gain Factor and Validation up to 5.5 THz

Abstract

Quantum cascade laser‐pumped terahertz (THz) gas lasers are at the edge of revolutionizing THz science where powerful yet tunable sources have long been lacking. Maybe one of the last remaining drawbacks to a wider use of these instruments lies in the lack of available databases of potentially lasing transitions for users. A new figure of merit, the molecular gain factor is proposed, that allows to discriminate transitions by their lasing potential. Using this factor, catalogs of THz laser lines of ammonia, both and , up to 10 THz are reported. Demonstration of the use of these two catalogs, and of the pertinence of the molecular gain factor, is made by experimentally observing 32 laser lines of and 5 lines of up to 5.5 THz. Prospects to generalize the use of this molecular gain factor to a wide range of molecules are discussed.