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Where is the Oxygen? Structural Analysis of α‐Humulene Oxidation Products by the Crystalline Sponge Method
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Citations
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References
2015
Year
EngineeringOxidation ResistanceOrganic ChemistryOxygen IsotopeChemistryCrystalline Sponge MethodChemical EngineeringRedox ChemistryStereoselective SynthesisAbsolute ConfigurationBiochemistryScaffold‐related CompoundsCatalysisα‐Humulene Oxidation ProductsNatural Product SynthesisEnantioselective SynthesisOxygen Reduction ReactionNatural SciencesStructural AnalysisChemical KineticsSynthetic Chemistry
Abstract Crystal structures of α‐humulene, a cyclic sesquiterpene, and its oxidized subproducts, were analyzed by the crystalline sponge method. Regio‐ and stereochemistry, including absolute configuration when a chiral oxidant was applied, and the stable conformations of all the scaffold‐related compounds were successfully determined for samples on a 5–50 μg scale.
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