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A Springlike 3D-Coordination Network That Shrinks or Swells in a Crystal-to-Crystal Manner upon Guest Removal or Readsorption
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2002
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Crystal StructureEngineeringMolecular BiologyChemistryGuest RemovalCrystal-to-crystal MannerSpringlike 3D-coordination NetworkDouble InterpenetrationCrystal FormationBiophysicsComplex MatterPhysicsCrystal MaterialCrystallographyCrystal Structure DesignHost-guest ChemistryPattern FormationUnprecedented Interlinked NetworkNatural SciencesSelf-assemblyGuest MoleculesApplied PhysicsCoordination ComplexMolecular ComplexCoordination Polymer
Double interpenetration: Guest molecules can control the formation of an unprecedented interlinked network consisting of zinc and a 3D tridentate ligand. The network shrinks when guest molecules are removed and swells when they are returned (see scheme). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2002/z18831_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.