A unified pH scale for all solvents: part I – intention and reasoning (IUPAC Technical Report)

Abstract

Abstract The definition of pH, its measurement and standard buffers, is well developed in aqueous solutions. Its definition in solvents other than water has been elaborated for a couple of solvents and their mixtures with water. However, the definition of a universal pH scale spanning all solvents and phases, not to mention standard procedures of measurement, is still a largely uncharted territory. UnipHied is a European collaboration and has the goal of putting the theoretical concept of an earlier introduced (2010) unified pH abs scale on a metrologically well-founded basis into practice. The pH abs scale enables the comparability of acidity between different phases. This article draws the connection of the concepts of unified acidity and secondary pH measurement.