New isoreticular phosphonate MOFs based on a tetratopic linker

Abstract

The tetratopic linker 1,1,2,2-tetrakis(4-phosphonophenyl)ethylene (H₈TPPE) was used to synthesize the three new porous metal-organic frameworks of composition [M₂(H₂O)₂(H₂TPPE)]·<i>x</i>H₂O (M = Al³⁺, Ga³⁺, Fe³⁺), denoted as M-CAU-53 under hydrothermal reaction conditions, using the corresponding metal nitrates as starting materials. The crystal structures of the compounds were determined <i>ab initio</i> from powder X-ray diffraction data, revealing small structural differences. Proton conductivity measurements were carried out, indicating different conductivity mechanisms. The differences in proton conductivity could be linked to the individual structures. In addition, a thorough characterization <i>via</i> thermogravimetry, elemental analysis, IR-spectroscopy as well as N₂- and H₂O-sorption is given.