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Infrared characterization of the products and the rate coefficient of the reaction between Criegee intermediate CH<sub>2</sub>OO and HCl

Wei-Che Liang, Pei-Ling Luo, Yuan‐Pern Lee

Physical Chemistry Chemical Physics · 2021 · 22 citations · 32 references

DOI

Concepts

Abstract

Infrared spectrum of chloromethyl hydroperoxide, the reaction product of Criegee intermediate CH<sub>2</sub>OO with HCl, was obtained. Secondary products CHClO and H<sub>2</sub>O were also observed. The rate coefficient was determined to be 4.8 × 10<sup>−11</sup> cm<sup>3</sup> molecule<sup>−1</sup> s<sup>−1</sup>.

References

32

Direct Kinetic Measurements of Criegee Intermediate (CH <sub>2</sub> OO) Formed by Reaction of CH <sub>2</sub> I with O <sub>2</sub>

Oliver Welz, John D. Savee, David L. Osborn et al. · Science · 2012 · 738 citations

, , +17

Direct kinetic measurement of the reaction of the simplest Criegee intermediate with water vapor

Wen Chao, Jun-Ting Hsieh, Chun-Hung Chang et al. · Science · 2015 · 342 citations

, , +14

Rate Coefficients of C1 and C2 Criegee Intermediate Reactions with Formic and Acetic Acid Near the Collision Limit: Direct Kinetics Measurements and Atmospheric Implications

Oliver Welz, Arkke J. Eskola, Leonid Sheps et al. · Angewandte Chemie International Edition · 2014 · 283 citations · Full text

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Research frontiers in the chemistry of Criegee intermediates and tropospheric ozonolysis

Craig A. Taatjes, Dudley E. Shallcross, Carl J. Percival · Physical Chemistry Chemical Physics · 2013 · 270 citations

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The physical chemistry of Criegee intermediates in the gas phase

David L. Osborn, Craig A. Taatjes · International Reviews in Physical Chemistry · 2015 · 269 citations · Full text

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