Hybrids of cationic [4]helicene and N-heterocyclic carbene as ligands for complexes exhibiting (chir)optical properties in the far red spectral window

Robert Tarrieu, I. Hernández Delgado, Francesco Zinna, Vincent Dorcet, Sophie Colombel‐Rouen, Christophe Crévisy, Olivier Baslé, Johann Bosson, Jérôme Lacour

Chemical Communications · 2021 · 20 citations · 40 references

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Abstract

A cationic Helicene-NHC hybrid is readily prepared and used for the construction of Rh<sup>I</sup>, Au<sup>I</sup> and Au<sup>III</sup> complexes. Ligand controlled chiroptical properties in the far-red spectral window are observed.

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