Viscoelastic Fluid Formed by Ultralong-Chain Erucic Acid–Base Ionic Liquid Surfactant Responds to Acid/Alkaline, CO₂, and Light

Abstract

As a leftover of grease processing, the efficient utilization of erucic acid is still a challenge. An alternative strategy is to develop erucic acid-derived surfactants. However, erucic acid-based ionic liquid surfactants were barely involved. Here, a novel ionic liquid surfactant, benzyltrimethylammonium erucate (ErBTA), was developed by a simple neutralization reaction, and its aggregations in the diluted and concentrated solution were systematically studied by surface tension, conductivity, rheology, and cryo-TEM techniques. The results showed that ErBTA has a very low metaling point (-7.03 °C) and possesses excellent water solubility (Krafft temperature <4 °C). ErBTA alone starts to form micelles at a very low concentration (0.028 mmol/L) and then to form worm-based viscoelastic fluid at 4.07 mmol/L without any additives, exhibiting excellent self-assembly ability and thickening ability. This viscoelastic fluid formed by ErBTA can simultaneously respond to three stimuli: common acid/alkaline, CO₂ gas, and light, accompanied by an interesting gel-sol conversion, reflecting microstructure transition from wormlike micelles to spherical micelles. Although in essence CO₂ and light also act as pH regulators in the current system, they provide more sophisticated approaches to tune pH. Such a viscoelastic fluid with the characteristics of easy availability, renewability of raw materials, the simplicity of fabrication, good water-solubility, and excellent thickening ability may be an attractive candidate for clean fracturing in oil/gas recovery and fluid drag reduction.