Interface and surface stabilization of the polarization in ferroelectric thin films

Abstract

Significance With an ever-increasing societal demand for energy for electronic devices and in the face of the current climate issues, the need for low-energy-consuming electronics has never been greater. Ferroelectrics are promising energy-efficient device components for digital information storage, with the functionality relying on the manipulation of their polarization in ultrathin films. Polar discontinuities at the thin film interfaces and surfaces, however, can cause loss of polarization and thus functionality. Here we show how the interface and surface influence the overall polarization of the thin film. We show that the structure of the interface and surface can be tailored toward a specific polarization direction and strength, and that great control in the engineering of ferroelectrics thin films can be achieved.