Physical Chemistry Chemical Physics · 2020 · 12 citations · 32 references
Natural SciencesChemical EngineeringChemistryElectrochemical EngineeringElectrochemistryInorganic ChemistryAdsorption At InterfacesElectrode MaterialsElectrode-electrolyte InterfacesIon SelectivityIon-selective ElectrodesSurface AdsorptionElectrode Ion AdsorptionIon AdsorptionIonic AdsorptionPore Size ControlPore Size EffectsPotential-dependent AdsorptionSelective AdsorptionSpecific Adsorption
). With no or a low applied voltage, the ion size dominates the selectivity, and with a high applied voltage, the strength of hydration dominates, although there were some exceptions. The ion specificity of the free energy barrier could be utilized in the selective adsorption of ions from multi-component electrolytes by controlling the pore size of the electrode and the applied voltage.
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