Small Methods · 2020 · 235 citations · 298 references
Natural SciencesChemical EngineeringChemistryCatalysisElectrochemical EngineeringElectrochemistryElectrochemical Energy ConversionOxygen EvolutionRedox-active MaterialsElectrocatalystsElectrocatalytic Oxygen EvolutionHydrogen EvolutionHydrogen Evolution ReactionHydrogen ProductionOxygen Evolution ReactionWater SplittingWater Splitting Catalysis
Abstract Hydrogen fuel is considered as one of the most clean renewable resources, warranting it a primary alternative to fossil fuels for future energy supplies. Electrocatalytic water splitting is an eco‐friendly technique for high‐purity hydrogen production. However, the sluggish dynamics of its two half‐reactions, hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), are tough challenges impeding the practical application of this technology. In these years, external field‐assisted HER and OER have attracted extensive research interests. Herein, the effects of various fields, including electric field, magnetic field, strain, and light, on electrocatalytic HER and OER are systematically discussed. The focus is how to integrate the external fields with the electrocatalytic systems and the fundamentals of field promoted HER/OER activities. In the end, the key challenges facing this rapidly progressing research field are highlighted and possible strategies addressing them are indicated.
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Branimir Radisavljevic, Jacopo Brivio, Valentina Giacometti et al. · Nature Nanotechnology · 2011 · 14.8K citations · Full text
Trends in the Exchange Current for Hydrogen Evolution
Jens K. Nørskov, Thomas Bligaard, Á. Logadóttir et al. · Journal of The Electrochemical Society · 2005 · 5.9K citations · Full text