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Mixed-ligand lanthanide complexes supported by ditopic bis(imino-methyl)-phenol/calix[4]arene macrocycles: synthesis, structures, and luminescence properties of [Ln2(L2)(MeOH)2] (Ln = La, Eu, Tb, Yb)

Steve Ullmann, Peter Hahn, Parvathy Mini, Kellie L. Tuck, Axel Kahnt, Bernd Abel, Matias Ezequiel Gutierrez Suburu, Cristian A. Strassert, Berthold Kersting

Dalton Transactions · 2020 · 21 citations · 56 references

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Abstract

H6L2 was found to be an effective dinucleating ligand for various Ln3+ ions forming luminescent, mixed-ligand complexes of composition [Ln2(L2)(MeOH)2] with one exchangeable coligand per seven-coordinated Ln site.

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Mixed-ligand lanthanide complexes supported by ditopic bis(imino-methyl)-phenol/calix[4]arene macrocycles: synthesis, structures, and luminescence properties of [Ln<sub>2</sub>(L<sup>2</sup>)(MeOH)<sub>2</sub>] (Ln = La, Eu, Tb, Yb)

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