Acta Crystallographica Section E Crystallographic Communications · 2020 · 12 citations · 20 references
Natural SciencesChemistryCrystal StructureOrganic ChemistrySurface ScienceCoordination ChemistryCrystal ChemistryCrystallographyIntermolecular InteractionsMolecular StructureMolecular SymmetryAromatic Stacking InteractionsBonding In Aromatic SystemsCrystal Structure RefinementDihedral AngleHydrogen Bond GeometryHydrogen Bond OrientationLigand Electronic Effectsπ Interactions
In the title compound, C 18 H 19 Cl 2 N 3 , the planes of the benzene rings subtend a dihedral angle of 77.07 (10)°. In the crystal, molecules are associated into inversion dimers via short Cl...Cl contacts [3.3763 (9) Å]. A Hirshfeld surface analysis indicates that the most important contact percentages for the different types of interactions are H...H (43.9%), Cl...H/H...Cl (22.9%), C...H/H...C (20.8%) and N...H/H...N (8.0%).
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