Concepedia

Origin of Sn(<scp>ii</scp>) oxidation in tin halide perovskites

Jorge Pascual, Giuseppe Nasti, Mahmoud H. Aldamasy, Joel A. Smith, Marion A. Flatken, Nga Phung, Diego Di Girolamo, Silver‐Hamill Turren‐Cruz, Meng Li, André Dallmann,

Materials Advances · 2020 · 223 citations · 19 references

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Concepts

Abstract

Tin-halide perovskites have great potential as photovoltaic materials, but their performance is hampered by undesirable oxidation of Sn(<sc>ii</sc>) to Sn(<sc>iv</sc>). NMR proves DMSO to be a main cause of oxidation.

References

19

Lead-free organic–inorganic tin halide perovskites for photovoltaic applications

Nakita K. Noel, Samuel D. Stranks, Antonio Abate et al. · Energy & Environmental Science · 2014 · 2.7K citations · Full text

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Monolithic all-perovskite tandem solar cells with 24.8% efficiency exploiting comproportionation to suppress Sn(ii) oxidation in precursor ink

Renxing Lin, Ke Xiao, Zhengyuan Qin et al. · Nature Energy · 2019 · 1.1K citations · Full text

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Biological impact of lead from halide perovskites reveals the risk of introducing a safe threshold

Junming Li, Hai–Lei Cao, Wen-Bin Jiao et al. · Nature Communications · 2020 · 682 citations · Full text

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Ultra-high open-circuit voltage of tin perovskite solar cells via an electron transporting layer design

Xianyuan Jiang, Fei Wang, Qi Wei et al. · Nature Communications · 2020 · 620 citations · Full text

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Phase Segregation in Cs-, Rb- and K-Doped Mixed-Cation (MA)<sub><i>x</i></sub>(FA)<sub>1–<i>x</i></sub>PbI<sub>3</sub> Hybrid Perovskites from Solid-State NMR

Dominik J. Kubicki, Daniel Prochowicz, Albert Hofstetter et al. · Journal of the American Chemical Society · 2017 · 379 citations · Full text

, , +17