Concepedia

Radical addition-polar termination cascade: efficient strategy for photoredox-neutral-catalysed cyclopropanation and Giese-type reactions of alkenyl <i>N</i>-methyliminodiacetyl boronates

Yongjun Liu, Wenping Luo, Jiali Wu, Yewen Fang, Yan Li, Xiaoping Jin, Li Zhang, Zongyong Zhang, Fenfen Xu, Chan Du

Organic Chemistry Frontiers · 2020 · 29 citations · 33 references

DOI

Concepts

Abstract

Silicate meets boronate: efficient cyclopropanation and Giese-type reactions of alkenyl <italic>N</italic>-methyliminodiacetyl boronates with alkyl silicates have been realized <italic>via</italic> a photoredox-neutral-catalysed radical-polar crossover process.

References

33

Shining Light on Photoredox Catalysis: Theory and Synthetic Applications

Joseph W. Tucker, Corey R. J. Stephenson · The Journal of Organic Chemistry · 2012 · 1.1K citations

, , +16

Fe-Catalyzed C–C Bond Construction from Olefins via Radicals

Julian C. Lo, Dongyoung Kim, Chung‐Mao Pan et al. · Journal of the American Chemical Society · 2017 · 432 citations · Full text

, , +15

Simple Access to Elusive α-Boryl Carbanions and Their Alkylation: An Umpolung Construction for Organic Synthesis

Kai Hong, Xun Liu, James P. Morken · Journal of the American Chemical Society · 2014 · 318 citations · Full text

, , +6

Photocarboxylation of Benzylic C–H Bonds

Qingyuan Meng, Tobias E. Schirmer, Anna Lucia Berger et al. · Journal of the American Chemical Society · 2019 · 316 citations · Full text

, , +17

Silicates as Latent Alkyl Radical Precursors: Visible‐Light Photocatalytic Oxidation of Hypervalent Bis‐Catecholato Silicon Compounds

Vincent Corcé, Lise‐Marie Chamoreau, Étienne Derat et al. · Angewandte Chemie International Edition · 2015 · 310 citations

, , +14