ACS Nano · 2020 · 43 citations · 51 references
Natural SciencesBiophysicsMaterials ScienceNanotechnologySurface ChemistrySurface ScienceLipid BilayersMembrane MechanicsNanomechanicsNanoparticle InterfacesNanoparticle SurfacesSurfactantsBlock Copolymer MicellesLubricationMicellesNanoparticle-membrane InteractionsNanoparticlesShear Stress ForcesSurface Force MeasurementsSurface Forces
)). However, while the boundary layer of single-tailed surfactant micelles degraded under moderate pressure, the homo-oligomeric micellar boundary layer was robust at all applied contact pressures in our study (up to about 5 MPa). We attribute the difference to the much greater energy required to remove a homo-oligomeric molecule from its micelle, resulting in far greater stability under pressure and shear.
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