Publication | Closed Access
Tuning on and off chemical- and photo-activity of exfoliated MoSe<sub>2</sub> nanosheets through morphologically selective “soft” covalent functionalization with porphyrins
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Citations
58
References
2020
Year
Materials ScienceInorganic ChemistryNanosheetEngineeringPhotoredox ProcessPhotochemistryNanomaterialsMechanistic PhotochemistryInorganic PhotochemistryHer ActivityPhotocatalysisPhotophysical PropertyType Ii HeterojunctionChemistryThiol-terminated PorphyrinsSupramolecular PhotochemistryFunctional MaterialsBiomolecular Engineering
Thiol-terminated porphyrins are covalently attached to 2D-MoSe<sub>2</sub> edges. The HER activity is enhanced (or suppressed) by the presence (or absence) of hydroxyl groups in the porphyrin. The porphyrin/MoSe<sub>2</sub> hybrid forms a type II heterojunction with improved photoactivity.
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