Concepedia

Phosphine-Free Ru-Catalyzed Regio- and Stereoselective Addition of Benzoic Acids to Trifluoromethylated Alkynes toward Facile Access to Trifluoromethyl Group-Substituted (<i>E</i>)-Enol Esters

Guangyuan Liu, Xingxing Zhang, Guanghua Kuang, Naihao Lu, Yang Fu, Yiyuan Peng, Qiang Xiao, Yirong Zhou

ACS Omega · 2020 · 15 citations · 62 references

DOIFull text

Open access

Concepts

Abstract

)-enol esters were readily obtained for a broad substrate scope in moderate to good yields with excellent regio- and stereoselectivities under mild reaction conditions.

References

62

Catalytic Markovnikov and anti‐Markovnikov Functionalization of Alkenes and Alkynes: Recent Developments and Trends

Matthias Beller, Jayasree Seayad, Annegret Tillack et al. · Angewandte Chemie International Edition · 2004 · 1.1K citations · Full text

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Recent advances in the trifluoromethylation methodology and new CF3-containing drugs

Wei Zhu, Jiang Wang, Shuni Wang et al. · Journal of Fluorine Chemistry · 2014 · 488 citations

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Metal Vinylidenes and Allenylidenes in Catalysis: Applications in Anti‐Markovnikov Additions to Terminal Alkynes and Alkene Metathesis

Christian Bruneau, Pierre H. Dixneuf · Angewandte Chemie International Edition · 2006 · 488 citations

, , +12

Electrophilic Trifluoromethylation by Copper-Catalyzed Addition of CF<sub>3</sub>-Transfer Reagents to Alkenes and Alkynes

Pär G. Janson, Ibrahim Ghoneim, Nadia O. Ilchenko et al. · Organic Letters · 2012 · 289 citations · Full text

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Highly Efficient Ruthenium-Based Catalytic Systems for the Controlled Free-Radical Polymerization of Vinyl Monomers

François Simal, Albert Demonceau, Alfred F. Noels · Angewandte Chemie International Edition · 1999 · 243 citations · Full text

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