Concepedia

Flexible cycloalkyl substituents in insertion polymerization with α-diimine nickel and palladium species

Shengyu Dai, Shuaikang Li, Guoyong Xu, Cheng Wu, Yudan Liao, Lihua Guo

Polymer Chemistry · 2020 · 116 citations · 34 references

DOI

Concepts

Abstract

The investigation of the relationship between the structure of the catalyst and the microstructure of the obtained polymer has attracted much attention and broad interest in the field of transition metal-catalyzed olefin polymerization.

References

34

New Pd(II)- and Ni(II)-Based Catalysts for Polymerization of Ethylene and .alpha.-Olefins

Lynda K. Johnson, Christopher M. Killian, Maurice Brookhart · Journal of the American Chemical Society · 1995 · 2.7K citations

, , +14

Synthesis of Branched Polyethylene Using (α-Diimine)nickel(II) Catalysts:  Influence of Temperature, Ethylene Pressure, and Ligand Structure on Polymer Properties

Derek P. Gates, Steven A. Svejda, Enrique Oñate et al. · Macromolecules · 2000 · 717 citations

, , +17

Mechanistic Studies of Pd(II)−α-Diimine-Catalyzed Olefin Polymerizations<sup>1</sup>

Daniel J. Tempel, Lynda K. Johnson, R. Leigh Huff et al. · Journal of the American Chemical Society · 2000 · 601 citations

, , +16

Palladium and Nickel Catalyzed Chain Walking Olefin Polymerization and Copolymerization

Lihua Guo, Shengyu Dai, Xuelin Sui et al. · ACS Catalysis · 2015 · 499 citations · Full text

, , +17

An N‐Heterocyclic Carbene Ligand with Flexible Steric Bulk Allows Suzuki Cross‐Coupling of Sterically Hindered Aryl Chlorides at Room Temperature

Gereon Altenhoff, Richard Goddard, Christian W. Lehmann et al. · Angewandte Chemie International Edition · 2003 · 470 citations

, , +12