Water Vapor Near‐UV Absorption: Laboratory Spectrum, Field Evidence, and Atmospheric Impacts

Abstract

Abstract Absorption of solar radiation by water vapor in the near‐UV region is a poorly understood but important issue in atmospheric science. To better understand water vapor near‐UV absorption, we constructed a cavity ring‐down spectrometer with bandwidth of 5 cm −1 (~0.05 nm) and obtained water vapor absorption cross sections at 1‐nm increments in the 290‐ to 350‐nm region. Water vapor displays structured absorption over this range with maximum and minimum cross sections of 8.4 × 10 −25 and 1.6 × 10 −25 cm 2 /molecule. Major water vapor absorption bands were observed at 293–295, 307–313, 319, 321–322, and 325 nm, with cross‐section values higher than 4.0 × 10 −25 cm 2 /molecule. To obtain further insight into major water vapor absorption bands, we measured water vapor absorption cross sections at 0.05‐nm intervals in the 292‐ to 296‐nm, 306‐ to 314‐nm, and 317‐ to 326‐nm region. Field UV residual spectra not only exhibited increased attenuation at higher atmospheric water vapor loadings but also showed structures suggested by the laboratory water vapor absorption spectrum. Spaceborne UV radiance spectra have spectral structures resembling the differential cross‐section spectrum constructed from the laboratory wavelength‐dependent water vapor absorption cross sections presented here. Incorporating water vapor absorption cross‐section data into a radiative transfer model yielded an estimated energy budget of 0.26 W/m 2 for the standard U.S. atmosphere and 0.76 W/m 2 for the tropics. This shows that water vapor near‐UV absorption is an important contributor for climate simulation and ozone retrievals.