Revisiting the Liquid–Liquid Phase Behavior of <i>n</i>-Alkanes and Ethanol

Abstract

-alkanes, the (liquid-liquid) critical point is shifted to higher temperatures and higher ethanol content. The data are analyzed numerically implying Ising criticality. The nonsymmetric shape of the phase body is considered in different approaches for describing the diameter by presuming (a) the validity of the rectilinear diameter rule, (b) a nonlinear diameter predicted in the theory of complete scaling, and (c) combining both concepts. The numerical analysis yields the critical temperature, the critical composition, the width, and the diameter of the phase diagrams. The results are compared with literature data sets from similar mixtures; these data are also evaluated in terms of the models applied here. Phase diagrams of 13 different sets of mixtures are measured and analyzed to extract general aspects of the behavior of the normal alkane-ethanol mixtures. A simple Flory-Huggins-like approach allows a semiquantitative description of the experimental results of the critical temperatures. Therefore, it confirms the picture of molecular ordering within the solutions.