Structure and electrochemical performance modulation of a LiNi_0.8Co_0.1Mn_0.1O₂ cathode material by anion and cation co-doping for lithium ion batteries

Abstract

Ni-rich layered transition metal oxides show great energy density but suffer poor thermal stability and inferior cycling performance, which limit their practical application. In this work, a minor content of Co and B were co-doped into the crystal of a Ni-rich cathode (LiNi_0.8Co_0.1Mn_0.1O₂) using cobalt acetate and boric acid as dopants. The results analyzed by XRD, TEM, XPS and SEM reveal that the modified sample shows a reduced energy barrier for Li⁺ insertion/extraction and alleviated Li⁺/Ni²⁺ cation mixing. With the doping of B and Co, corresponding enhanced cycle stability was achieved with a high capacity retention of 86.1% at 1.0C after 300 cycles in the range of 2.7 and 4.3 V at 25 °C, which obviously outperformed the pristine cathode (52.9%). When cycled after 300 cycles at 5C, the material exhibits significantly enhanced cycle stability with a capacity retention of 81.9%. This strategy for the enhancement of the electrochemical performance may provide some guiding significance for the practical application of high nickel content cathodes.