Chemical Communications · 2019 · 24 citations · 27 references
Natural SciencesChemistryCatalysisOrganic ChemistryCatalytic MechanismsRedox CatalysisRedox ChemistryRedox ReactionsCarbene Transfer ReactionsRedox SynthesisTransition Metal-catalyzed Synthesis
Herein, we report on rhodium catalysed carbene transfer reactions of diazoesters with diselenides that result in the formal insertion reaction of the carbene fragment into the Se-Se bond to give seleno-ketals in up to 96% yield (35 examples) via an ionic mechanism.
27
Conservation of orbital symmetry
Roald Hoffmann, R. B. Woodward · Accounts of Chemical Research · 1968 · 654 citations
Blue‐Light‐Induced Carbene‐Transfer Reactions of Diazoalkanes
Renè Hommelsheim, Yujing Guo, Zhen Yang et al. · Angewandte Chemie International Edition · 2018 · 275 citations