Rhodium(<scp>iii</scp>)-catalyzed cascade reactions of benzoic acids with dioxazolones: discovery of 2,5-substituted benzoxazinones as AIE molecules

Abstract

A rhodium-catalyzed cascade reaction of benzoic acids with 1,4,2-dioxazol-5-ones was studied. The carboxyl group enabled a double C-H amidation followed by further intramolecular cyclization to afford 2,5-substituted benzoxazinones, which exhibited aggregation-induced emission (AIE) properties with a promising excited-state intramolecular proton-transfer (ESIPT) phenomenon.