Concepedia

Photo–nickel dual catalytic benzoylation of aryl bromides

Tobias E. Schirmer, Alexander Wimmer, Florian Weinzierl, Burkhard König

Chemical Communications · 2019 · 39 citations · 33 references

DOI

Concepts

Abstract

The dual catalytic arylation of aromatic aldehydes by aryl bromides using UV-irradiation and a nickel catalyst is reported. The reaction product serves as a photocatalyst and a hydrogen atom transfer agent for this transformation.

References

33

Dual Catalysis Sees the Light: Combining Photoredox with Organo‐, Acid, and Transition‐Metal Catalysis

Matthew N. Hopkinson, Basudev Sahoo, Jun‐Long Li et al. · Chemistry - A European Journal · 2014 · 698 citations

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Direct C(sp<sup>3</sup>)–H Cross Coupling Enabled by Catalytic Generation of Chlorine Radicals

Benjamin J. Shields, Abigail G. Doyle · Journal of the American Chemical Society · 2016 · 652 citations · Full text

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Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings

Osvaldo Gutiérrez, John C. Tellis, David N. Primer et al. · Journal of the American Chemical Society · 2015 · 604 citations · Full text

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Photochemical Nickel-Catalyzed C–H Arylation: Synthetic Scope and Mechanistic Investigations

Drew R. Heitz, John C. Tellis, Gary A. Molander · Journal of the American Chemical Society · 2016 · 523 citations · Full text

, , +16

<i>sp</i><sup>3</sup> C–H Arylation and Alkylation Enabled by the Synergy of Triplet Excited Ketones and Nickel Catalysts

Yangyang Shen, Yiting Gu, Rubén Martı́n · Journal of the American Chemical Society · 2018 · 367 citations

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