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Asymmetric Synthesis of Aziridinyl Phosphonates Using Darzens-Type Reaction of Chloromethyl Phosphonate to Chiral Sulfinimines
22
Citations
8
References
2000
Year
EngineeringAsymmetric SynthesisChiral SulfiniminesChloromethyl PhosphonateOrganic ChemistryAbstract Darzens-type ReactionStereoselective SynthesisChemistryPharmacologyAsymmetric CatalysisChemical DerivativeSynthetic ChemistryEnantioselective SynthesisBiomolecular EngineeringGood Yields
Abstract Darzens-type reaction of chloromethyl phosphonate with (S)-(+)-N-sulfinimines gave (Ss, 2S, 3R)-diethyl 3-aryl-2-N-(p-toluenesulfinyl)aziridinyl-phosphonate (3) in good yields.
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