Metallic Samarium and Iodine in Alcohol. Deacylation and Dealkyloxycarbonylation of Protected Alcohols and Lactams - Concepedia

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Metallic Samarium and Iodine in Alcohol. Deacylation and Dealkyloxycarbonylation of Protected Alcohols and Lactams

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References

1995

Year

Reiko Yanada, Nobuyuki Negoro, Kiyoshi Bessho, Kazuo Yanada

HalogenationChemical EngineeringDerivative (Chemistry)EngineeringAlkyloxycarbonyl-protected AlcoholsMetallic SamariumOrganic ChemistryNeutral ConditionsChemistryPharmacologyChemical DerivativeSynthetic ChemistryProtected Alcohols

Abstract

Acyl- or alkyloxycarbonyl-protected alcohols or amides are deprotected easily and selectively in high yields with metallic samarium and iodine in alcohol under mild and neutral conditions.