Concepedia

Nickel-Catalyzed Hydrosilylation/Cyclization of Difluoro-Substituted 1,6-Enynes

Manabu Takachi, Naoto Chatani

Organic Letters · 2010 · 41 citations · 16 references

DOI

Concepts

Abstract

Ni-catalyzed hydrosilylative cyclization of difluoro-substituted 1,6-enynes can be carried out. The presence of a geminal-difluoromethylene group at an alkene terminus in enynes is essential for the reaction to proceed.

References

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