Concepedia

A Convenient Synthesis of Chiral Nonracemic Vinyl Aziridines

Daniel Morton, David Pearson, Robert A. Field, Robert A. Stockman

Organic Letters · 2004 · 87 citations · 23 references

DOI

Concepts

Abstract

[reaction: see text] The preparation of a range of alkyl and aryl chiral vinyl aziridines was achieved in high yield and stereoselectivity, and with excellent diastereoselectivity, by reaction of tert-butylsulfinylimines with the ylide derived from S-allyl tetrahydrothiophenium bromide.

References

23

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David Tanner · Angewandte Chemie International Edition in English · 1994 · 1.1K citations

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Nucleophilic ring opening of aziridines

Xiaoyan Hu · Tetrahedron · 2004 · 881 citations

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William McCoull, Franklin A. Davis · Synthesis · 2000 · 579 citations

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Synthesis of Enantiomerically Pure <i>N</i>-<i>tert</i>-Butanesulfinyl Imines (<i>tert</i>-Butanesulfinimines) by the Direct Condensation of <i>tert</i>-Butanesulfinamide with Aldehydes and Ketones

Guangcheng Liu, Derek A. Cogan, Timothy D. Owens et al. · The Journal of Organic Chemistry · 1999 · 499 citations

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Asymmetric synthesis of chiral amines by highly diastereoselective 1,2-additions of organometallic reagents to N-tert-butanesulfinyl imines

Derek A. Cogan, Guangcheng Liu, Jonathan A. Ellman · Tetrahedron · 1999 · 334 citations

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