Phosphorothioate Synthesis Based on the Redox Reaction of Phosphite with Tellurium(IV) Chloride - Concepedia

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Phosphorothioate Synthesis Based on the Redox Reaction of Phosphite with Tellurium(IV) Chloride

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1995

Year

Yutaka Watanabe, Shinji Inoue, Takashi Yamamoto, Shoichiro Ozaki

Inorganic ChemistryChemical EngineeringEngineeringPhosphoric Thiol EstersPhosphorous TriestersOrganic ChemistryChemistryRedox-type ReactionPhosphoreneRedox ReactionBiomolecular EngineeringPhosphorothioate Synthesis

Abstract

Phosphoric thiol esters are conveniently prepared by the treatment of phosphorous triesters with thiols in the presence of tellurium(IV) chloride in a redox-type reaction.