Concepedia

N → C<sub>3</sub> migration of dichlorophosphino group in the phosphorylation of N‐unsubstituted indole with phosphorus trichloride

Aleksandra A. Chaikovskaya, Yurii V. Dmytriv, Nadiya V. Shevchuk, Radomyr V. Smaliy, Aleksander M. Pinchuk, Andrey A. Tolmachev

Heteroatom Chemistry · 2009 · 11 citations · 4 references

DOI

Concepts

Abstract

Abstract A N → C 3 migration of the dichlorophosphino group has been revealed in the phosphorylation of unsubstituted indole with phosphorus trichloride. Several 3‐phosphorylated NH‐indole derivatives have thus been obtained and N‐acylation of one of the products has been performed. © 2009 Wiley Periodicals, Inc. Heteroatom Chem 20:235–239, 2009; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20540

References

4

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An efficient catalyst system for diaryl ether synthesis from aryl chlorides

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C-phosphorylation of n-methylpyrrole

Sergey P. Ivonin, Tetjana E. Terikovska, A. A. Chaikovskaya et al. · Heteroatom Chemistry · 1999 · 18 citations

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N → C<sub>2</sub> → C<sub>3</sub> migration of the dichlorophosphino group in the synthesis of phosphorylated NH‐pyrroles

Aleksandra A. Chaikovskaya, Yurii V. Dmytriv, Nadiya V. Shevchuk et al. · Heteroatom Chemistry · 2008 · 17 citations

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