N → C<sub>3</sub> migration of dichlorophosphino group in the phosphorylation of N‐unsubstituted indole with phosphorus trichloride

Abstract

Abstract A N → C 3 migration of the dichlorophosphino group has been revealed in the phosphorylation of unsubstituted indole with phosphorus trichloride. Several 3‐phosphorylated NH‐indole derivatives have thus been obtained and N‐acylation of one of the products has been performed. © 2009 Wiley Periodicals, Inc. Heteroatom Chem 20:235–239, 2009; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20540

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